(Rabu, 18 September dinihari WIB)

GRUP A
| Manchester United 4-2 Bayer Leverkusen
(Rooney 22′,70′, Van Persie 59′, Valencia 79′ – Rofles 54′, Ömer Toprak 88′)

| Real Sociedad 0-2 Shakhtar Donetsk
(Alex Teixeira 65′,87′)

GRUP B:
| Galatasaray 1-6 Real Madrid
(Isco 33′, Benzema 54′,81′, Ronaldo 63′,66′,90+1′, Umut Bulut 84′)

| FC Copenhagen 1-1 #Juventus
(Nicolai Jorgensen 14′ – Fabio Quagliarella 54′)

GRUP C
| SL Benfica 2-0 Anderlecht
(Djuričić 4′, Luisão 30′)

| Olympiacos 1-4 PSG
(Weiss 25′ – Cavani 19′, Thiago Motta 68′,73′, Marquinhos)

GRUP D
| Bayern Munich 3-0 CSKA Moskow
(Alaba 4′, Mandžukić 41′, Robben 68′)

| Viktoria Plzen 0-3 Manchester City
(Dzeko 48′, Y. Toure 53′, Aguero 58′)

(Kamis, 19 September dinihari WIB)
GRUP E:
| Schalke 3-0 Steaua Bucuresti
(Uchida 67′, Boateng 78′, Draxler 85′)

| Chelsea FC 1-2 FC Basel
(Oscar 45′ – Salah 71′, Streller 81′)

GRUP F:
| #Napoli 2-1 Borussia Dortmund
(Gonzalo Higuain 29′, Lorenzo Insigne 67′ – Juan Zuniga 87-og)

| OLympique Marseille 1-2 Arsenal
(Ayew 90+3-pen – Walcott 65′, Ramsey 83′)

GRUP G:
| Austria Wien 0-1 FC Porto
(Lucho González 55′)

| Atlético Madrid 3-1 Zenit St. Petersburg
(Miranda 40′, Arda Turan 64′, Baptistão 80′ – Hulk 58′)

GRUP H:
| AC Milan 2-0 Celtic FC
(Cristian Zapata 82′, Sulley Muntari 86′)

| Barcelona 4-0 Ajax Amsterdam
(Messi 22′,55′,75′, Pique 69′)